Rational design of cathode structure based on free-standing S/rGO/CNT nanocomposite for Li-S batteries

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dc.authorid0000-0003-1895-3822
dc.contributor.authorKöse, Hilal
dc.contributor.authorŞahin Kurt, Büşra
dc.contributor.authorDombaycıoğlu, Şeyma
dc.contributor.authorAydın, Ali Osman
dc.date.accessioned2020-10-05T06:21:55Z
dc.date.available2020-10-05T06:21:55Z
dc.date.issued2020
dc.departmentİstanbul Medipol Üniversitesi, Eczacılık Fakültesi, Temel Eczacılık Bilimleri Bölümü, Analitik Kimya Ana Bilim Dalı
dc.description.abstractSulfur / reduced graphene oxide / carbon nanotube (S/rGO/CNT) composite cathodes were fabricated as laminar-structured free-standing papers to develop high-capacity lithium sulfur batteries (Li-S). Here, the rGO content improved the electronic conductivity and acted as a buffer to accommodate volumetric expansion of sulfur together with CNTs. In this study, it was aimed to benefit from the synergistic effect of the hybrid structure of rGO and CNT, and to determine the effect of rGO and CNT ratio on the S/rGO/CNT cathode capacity. For this purpose, the free-standing, flexible and binder-less paper cathodes were rationally designed by using different rGO/CNT ratios via a vacuum filtration method. To characterize the fabricated S/rGO/CNT cathodes, thermogravimetric analysis (TGA), field emission gun scanning electron microscopy (FEG-SEM), energy dispersive x-ray spectrometer (EDS), x-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy and electrochemical performance tests were used. In the fabrication of S/rGO/CNT cathodes, the obtained results showed that the use of 2:1 rGO/CNT ratio exhibited more mesoporous, well-designed laminar structure and higher discharge capacity according to 1:1 and 1:2 rGO/CNT ratios. As a result, the most effective cathode was achieved at 0.1C after 300 cycles, exhibiting a 701 mA h g(-1) discharge capacity. According to the obtained results, the fabricated cathode structures could be promise as novel high-performance Li-S cathode materials with a facile method.
dc.description.sponsorshipTürkiye Bilimsel ve Teknolojik Araştırma Kurumu (TÜBİTAK)en_US
dc.identifier.citationKöse, H., Şahin Kurt, B., Dombaycıoğlu, Ş. ve Aydın, A. O. (2020). Rational design of cathode structure based on free-standing S/rGO/CNT nanocomposite for Li-S batteries. Synthetic Metals, 267. https://dx.doi.org/10.1016/j.synthmet.2020.116471
dc.identifier.doi10.1016/j.synthmet.2020.116471
dc.identifier.issn0379-6779
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://dx.doi.org/10.1016/j.synthmet.2020.116471
dc.identifier.urihttps://hdl.handle.net/20.500.12511/5901
dc.identifier.volume267
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science
dc.relation.ispartofSynthetic Metalsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.relation.tubitakinfo:eu-repo/grantAgreement/TUBITAK/SOBAG/118M265
dc.rightsinfo:eu-repo/semantics/embargoedAccess
dc.subjectS/Rgo/CNT Composite Cathodes
dc.subjectLaminar Structure
dc.subjectRgo/CNT Rational Design
dc.subjectFree-Standing Papers
dc.subjectLi-S Batteries
dc.titleRational design of cathode structure based on free-standing S/rGO/CNT nanocomposite for Li-S batteries
dc.typeArticle

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