Investigation on structural and adsorptive features of BaO modified zeolite powders prepared by ball milling technique: Removal of tetracycline and various organic contaminants

dc.contributor.authorKanmaz, Nergiz
dc.contributor.authorBuğdaycı, Mehmet
dc.contributor.authorDemirçivi, Pelin
dc.date.accessioned2023-04-07T09:44:51Z
dc.date.available2023-04-07T09:44:51Z
dc.date.issued2023
dc.departmentİstanbul Medipol Üniversitesi, İMÜ Meslek Yüksekokulu, İnşaat Teknolojisi Ana Bilim Dalı
dc.description.abstractIn the current study, the removal of tetracycline (TC) antibiotic via BaO-doped zeolite (80BaO@zeolite), which synthesized by ball-mill technique, from water by adsorption process was studied. The structure and properties of 80BaO@zeolite was determined by XRD, FTIR, SEM and BET/N2. TC adsorption capacity of 71.4 mg g?1 was obtained for 80BaO@zeolite. The Langmuir isotherm model was found to be compatible for 80BaO@zeolite. The kinetic results indicate that the adsorption rate is compatible with the pseudo second order model and the time for the adsorption to reach equilibrium was achieved as 360 min. Maximum TC removal was obtained at pH:10, in the presence of NaCl and CaCl2 salts, and compared to in tap water drinking water and distilled water. The sorption process has shown thermodynamically exothermic and spontaneous nature. The desorption of TC molecules attached to the 80BaO@zeolite surface was investigated using different eluents. The 88% TC removal and 94% TC recovery rates achieved in the first cycle with the 1 M NaOH eluent decreased to 72% and 70%, respectively, in the fourth cycle. High adsorption capacities of 161.3 mg g?1, 59.3 mg g?1 and 85.5 mg g?1were obtained in the removal of malachite green, murexide and basic violet-16, respectively.
dc.identifier.citationKanmaz, N., Buğdaycı, M. ve Demirçivi, P. (2023). Investigation on structural and adsorptive features of BaO modified zeolite powders prepared by ball milling technique: Removal of tetracycline and various organic contaminants. Microporous and Mesoporous Materials, 354. https://dx.doi.org/10.1016/j.micromeso.2023.112566
dc.identifier.doi10.1016/j.micromeso.2023.112566
dc.identifier.issn1387-1811
dc.identifier.issn1873-3093
dc.identifier.scopus2-s2.0-85151242434
dc.identifier.scopusqualityQ4
dc.identifier.urihttps://dx.doi.org/10.1016/j.micromeso.2023.112566
dc.identifier.urihttps://hdl.handle.net/20.500.12511/10821
dc.identifier.volume354
dc.identifier.wos000994588300001en_US
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorBuğdaycı, Mehmet
dc.language.isoen
dc.publisherElsevier B.V.
dc.relation.ispartofMicroporous and Mesoporous Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/embargoedAccess
dc.subjectAdsorption
dc.subjectAntibiotic
dc.subjectBarium Oxide
dc.subjectDesorption
dc.subjectZeolite
dc.titleInvestigation on structural and adsorptive features of BaO modified zeolite powders prepared by ball milling technique: Removal of tetracycline and various organic contaminants
dc.typeArticle

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