Fabrication of nickel manganese cobalt oxide (NMCO) anodes for lithium-ion batteries via hydrothermal process

dc.contributor.authorSolmaz, Reyhan
dc.contributor.authorKarahan, Billur Deniz
dc.contributor.authorKeleş, Özgül
dc.date.accessioned2020-10-21T10:59:00Z
dc.date.available2020-10-21T10:59:00Z
dc.date.issued2020
dc.departmentİstanbul Medipol Üniversitesi, Mühendislik ve Doğa Bilimleri Fakültesi, İnşaat Mühendisliği Bölümü
dc.description.abstractNickel manganese cobalt oxide (NMCO) powders have been fabricated by hydrothermal method followed by a calcination. The present work reports for the first time in the open literature, the effects of ammonium fluoride (NH4F) amount and calcination temperature on the NMCO powder's size and morphology. In this regard, the NMCO composite powders are designed to optimize their performances as anode materials for lithium ion batteries. The morphology, composition and structure of powders have been characterized by scanning electron microscopy, X-ray fluorescence and X-ray diffractometry, respectively. Cyclic voltammetry, galvanostatic and impedance spectroscopy tests have been employed to investigate the lithiation mechanism of the composite electrode. The results reveal that the lowest amount of NH4F (1.5 mmol) in the precursor solution and the lowest calcination temperature (250 degrees C) lead to form NMCO rods with 100 nm diameter and 3-5 mu m length. This newly designed rod-shaped NMCO powder presents a high rate performance. The average discharge/charge capacities are 1224/1129, 968/939, 856/826, and 744/712 mAh g(-1)when the current load increases from 50 to 100, 200 and 400 mA g(-1), respectively.
dc.identifier.citationSolmaz, R., Karahan, B. D. ve Keleş, Ö. (2020). Fabrication of nickel manganese cobalt oxide (NMCO) anodes for lithium-ion batteries via hydrothermal process. Journal of Applied Electrochemistry, 50(10), 1079-1089. https://dx.doi.org/10.1007/s10800-020-01462-9
dc.identifier.doi10.1007/s10800-020-01462-9
dc.identifier.endpage1089
dc.identifier.issn0021-891X
dc.identifier.issn1572-8838
dc.identifier.issue10
dc.identifier.scopusqualityQ2
dc.identifier.startpage1079
dc.identifier.urihttps://dx.doi.org/10.1007/s10800-020-01462-9
dc.identifier.urihttps://hdl.handle.net/20.500.12511/5954
dc.identifier.volume50
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Applied Electrochemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/embargoedAccess
dc.subjectLithium-Ion Battery
dc.subjectAnode
dc.subjectHydrothermal Method
dc.subjectNickel Manganese Cobalt Oxide
dc.subjectNMCO
dc.titleFabrication of nickel manganese cobalt oxide (NMCO) anodes for lithium-ion batteries via hydrothermal process
dc.typeArticle

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