Synthesis of CuBDC metal-organic framework supported zinc oxide via ball-milling technique for enhanced adsorption of Orange-II

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dc.contributor.authorYardımcı, Batuhan
dc.contributor.authorKanmaz, Nergiz
dc.contributor.authorBuğdaycı, Mehmet
dc.contributor.authorDemirçivi, Pelin
dc.date.accessioned2024-03-20T06:31:24Z
dc.date.available2024-03-20T06:31:24Z
dc.date.issued2024
dc.departmentİstanbul Medipol Üniversitesi, İMÜ Meslek Yüksekokulu, İnşaat Teknolojisi Ana Bilim Dalı
dc.description.abstractFor the first time, copper-based metal-organic framework (CuBDC) supported ZnO composite was successfully prepared by the ball-milling method for effective adsorption of anionic azo orange-II (OII) dye. After comparing the OII adsorption performances of ZnO and composites, with two different CuBDC support ratios, focused on the investigation of 1:1 CuBDC@ZnO. The crystal structures, physicochemical properties, and surface morphologies of the adsorbents were characterized by XRD, FTIR, SEM-EDX, and BET analyses. The adsorption process fitted the Langmuir isotherm model (R2=0.98) and the monolayer adsorption capacity of 1:1 CuBDC@ZnO composite was found to be 132.12 mg g?1. The adsorption process was well described by the pseudo-second-order model, which indicates the adsorption process of 1:1 CuBDC@ZnO composite on OII is chemisorption. Moreover, 1:1 CuBDC@ZnO composite can be an alternative as an effective and innovative adsorbent for the removal of toxic OII dye contaminant.
dc.identifier.citationYardımcı, B., Kanmaz, N., Buğdaycı, M. ve Demirçivi, P. (2024). Synthesis of CuBDC metal-organic framework supported zinc oxide via ball-milling technique for enhanced adsorption of Orange-II. Surfaces and Interfaces, 46. https://dx.doi.org/10.1016/j.surfin.2024.104122
dc.identifier.doi10.1016/j.surfin.2024.104122
dc.identifier.issn2468-0230
dc.identifier.scopus2-s2.0-85186849626
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://dx.doi.org/10.1016/j.surfin.2024.104122
dc.identifier.urihttps://hdl.handle.net/20.500.12511/12378
dc.identifier.volume46
dc.identifier.wos001222157100001en_US
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorBuğdaycı, Mehmet
dc.language.isoen
dc.publisherElsevier B. V.
dc.relation.ispartofSurfaces and Interfacesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/embargoedAccess
dc.subjectAdsorption
dc.subjectBall-Milling
dc.subjectCuBDC
dc.subjectMetal-Organic Framework
dc.subjectOrange-II
dc.subjectZinc Oxide
dc.titleSynthesis of CuBDC metal-organic framework supported zinc oxide via ball-milling technique for enhanced adsorption of Orange-II
dc.typeArticle

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