Electroless nickel-plated ferrochromium flue dust as anode material for lithium-ion batteries

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dc.contributor.authorAshraf, Humza
dc.contributor.authorKarahan, Billur Deniz
dc.date.accessioned2024-01-18T09:38:23Z
dc.date.available2024-01-18T09:38:23Z
dc.date.issued2023
dc.departmentİstanbul Medipol Üniversitesi, Rektörlük, Sağlık Bilim ve Teknolojileri Araştırma Enstitüsü
dc.description.abstractThe flue dust of the electric arc furnace is a waste product generated in the production of ferrochromium alloy. It consists of various transition metal oxides and silicates. In this study, innovatively, it is proposed to apply electroless nickel plating and then high-energy ball milling to evaluate the waste in question as electrode material in battery technology. Therefore, the flue dust (sample 1), the electroless nickel-plated (sample 2), and the electroless nickel-plated then high-energy ball-milled (sample 3) flue dust are characterized morphologically, structurally, and chemically. Cyclic voltammetry is performed to investigate their lithiation mechanisms. Negative symmetric cells are assembled to record their impedances. The SEM, XRD, and XPS results of sample 3 show that a nickel layer is successfully deposited on the flue dust. Electrochemical test results reveal that due to the catalytic effect and electrochemically inactive behavior (versus lithium) of nickel, the electrode/electrolyte interface reactions are modified, electron transfer along the electrode is facilitated and electrochemical induced agglomeration in cycling is prevented. Moreover, decreasing the particle size by ball milling increases the stress accommodation ability of the electrode. Hence, crack formation and delamination of sample 3 are also restricted.
dc.description.sponsorshipIstanbul Medipol Universityen_US
dc.identifier.citationAshraf, H. ve Karahan, B. D. (2023). Electroless nickel-plated ferrochromium flue dust as anode material for lithium-ion batteries. Journal of Materials Engineering and Performance, 32(20), 9029-9039. https://dx.doi.org/10.1007/s11665-022-07772-7
dc.identifier.doi10.1007/s11665-022-07772-7
dc.identifier.endpage9039
dc.identifier.issn1059-9495
dc.identifier.issn1544-1024
dc.identifier.issue20
dc.identifier.scopus2-s2.0-85147350228
dc.identifier.scopusqualityQ2
dc.identifier.startpage9029
dc.identifier.urihttps://dx.doi.org/10.1007/s11665-022-07772-7
dc.identifier.urihttps://hdl.handle.net/20.500.12511/12168
dc.identifier.volume32
dc.identifier.wos000926115100003en_US
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorKarahan, Billur Deniz
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Materials Engineering and Performanceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/embargoedAccess
dc.subjectEnergy
dc.subjectGreen Industry
dc.subjectLithium
dc.subjectNanomaterials
dc.subjectPowder Metallurgy
dc.subjectSurface Modification
dc.titleElectroless nickel-plated ferrochromium flue dust as anode material for lithium-ion batteries
dc.typeArticle

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