Promoting photo-fenton catalytic performance of novel NiZrO3-type perovskite: Optimization with response surface methodology

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dc.contributor.authorKanmaz, Nergiz
dc.contributor.authorBuğdaycı, Mehmet
dc.date.accessioned2023-10-06T08:28:29Z
dc.date.available2023-10-06T08:28:29Z
dc.date.issued2024
dc.departmentİstanbul Medipol Üniversitesi, İMÜ Meslek Yüksekokulu, İnşaat Teknolojisi Ana Bilim Dalı
dc.description.abstractPerovskite type NiZrO3 photocatalysts were synthesized by ball-mill technique and used for tetracycline (TC) degradation. NiZrO3 milled for 6 h (NiZrO3-6h) had significant-99 % photo-Fenton catalytic activity on TC removal It was determined that the characteristic peaks of NiZrO3 with XRD, spherical shaped structures with SEM, no organic peaks in the structure with FTIR, band gap of 4.40 eV with DRS and stable colloids with zeta potential. Response surface methodology (RSM) including Box-Behnken design (BBD) was applied to examine H2O2, Fe2+ and initial TC concentration effects on degradation and it was observed that H2O2 concentration had the highest effect on TC degradation. The photocatalytic efficacy of NiZrO3 could still eliminate 78 % of initial antibiotic molecules after eight-cycle. The application potential for Photo-Fenton assisted NiZrO3-6h was also observed in the degradation of other organic pollutants such as drugs (salicylic acid, ciprofloxacin, ampicillin) and dye (methylene blue, rhodamine-b, orange-II, malachite green, crystal violet). It suggests that the mechanochemically synthesized NiZrO3-6h perovskite could be suitable for its effective use in the photo-Fenton catalytic system.
dc.identifier.citationKanmaz, N. ve Buğdaycı, M. (2024). Promoting photo-fenton catalytic performance of novel NiZrO3-type perovskite: Optimization with response surface methodology. Journal of Molecular Structure, 1295. https://doi.org/10.1016/j.molstruc.2023.136718
dc.identifier.doi10.1016/j.molstruc.2023.136718
dc.identifier.issn0022-2860
dc.identifier.scopus2-s2.0-85172193076
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2023.136718
dc.identifier.urihttps://hdl.handle.net/20.500.12511/11533
dc.identifier.volume1295
dc.identifier.wos001088768100001en_US
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorBuğdaycı, Mehmet
dc.language.isoen
dc.publisherElsevier B.V.
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/embargoedAccess
dc.subjectBall-Milling
dc.subjectNiZrO3
dc.subjectPerovskite
dc.subjectPhoto-Fenton
dc.subjectPhotocatalysis
dc.subjectTetracycline
dc.titlePromoting photo-fenton catalytic performance of novel NiZrO3-type perovskite: Optimization with response surface methodology
dc.typeArticle

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