dc.contributor.author | Torabfam, Milad | |
dc.contributor.author | Nejatpour, Mona | |
dc.contributor.author | Fidan, Tuçe | |
dc.contributor.author | Kurt, Hasan | |
dc.contributor.author | Yüce, Meral | |
dc.contributor.author | Bayazıt, Mustafa Kemal | |
dc.date.accessioned | 2022-11-14T09:02:49Z | |
dc.date.available | 2022-11-14T09:02:49Z | |
dc.date.issued | 2022 | en_US |
dc.identifier.citation | Torabfam, M., Nejatpour, M., Fidan, T., Kurt, H., Yüce, M. ve Bayazıt, M. K. (2022). A microwave-powered continuous fluidic system for polymer nanocomposite manufacturing: A proof-of-concept study. Green Chemistry, 24(7), 2812-2824. https://doi.org/10.1039/d1gc04711f | en_US |
dc.identifier.issn | 1463-9262 | |
dc.identifier.issn | 1463-9270 | |
dc.identifier.uri | https://doi.org/10.1039/d1gc04711f | |
dc.identifier.uri | https://hdl.handle.net/20.500.12511/9954 | |
dc.description.abstract | Continuous manufacturing of pure nanocrystals with a narrow size distribution in a polymer matrix is very challenging, although it is highly crucial to get their full potential for advanced applications. A long-lasting nanocomposite (NC) manufacturing challenge is, for the first time, overcome by a microwave-powered fluidic system (MWFS). The effect of microwave power (MWP), flow rate, and the concentration of the reagents are systematically studied. The nylon-6 NC bearing evenly distributed silver nanoparticles (AgNPs) with a mean size of similar to 2.59 +/- 0.639 nm is manufactured continuously in similar to 2 min at similar to 50-55 degrees C using a green solvent, formic acid. The AgNP size becomes smaller when increasing the polymer concentration gradually. Small NPs with a narrow size distribution are produced at high MWP (40 W), but large ones with a broad size distribution at low MWP (10 W). The nylon-6 crystallinity is NP size-dependent, and the gamma-phase (pseudo-hexagonal crystal) is dominant in the presence of small NPs as against the large counterparts. Given the small-sized AgNPs in the MWF-manufactured NCs, the antibacterial activity tests with Escherichia coli, Staphylococcus aureus, and Pseudomonas aeruginosa show superior activity compared to that of the large AgNP-bearing (similar to 50 nm) NCs produced in a conventional heating fluidic system. The proposed MWFS can manufacture other added-value NCs continuously. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Royal Society of Chemistry | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Polymer Nanocomposite Manufacturing | en_US |
dc.subject | Fluidic System | en_US |
dc.subject | Microwave | en_US |
dc.title | A microwave-powered continuous fluidic system for polymer nanocomposite manufacturing: A proof-of-concept study | en_US |
dc.type | article | en_US |
dc.relation.ispartof | Green Chemistry | en_US |
dc.department | İstanbul Medipol Üniversitesi, Mühendislik ve Doğa Bilimleri Fakültesi, Endüstri Mühendisliği Bölümü | en_US |
dc.department | İstanbul Medipol Üniversitesi, Rektörlük, Sağlık Bilim ve Teknolojileri Araştırma Enstitüsü | en_US |
dc.authorid | 0000-0002-1677-644X | en_US |
dc.identifier.volume | 24 | en_US |
dc.identifier.issue | 7 | en_US |
dc.identifier.startpage | 2812 | en_US |
dc.identifier.endpage | 2824 | en_US |
dc.relation.tubitak | info:eu-repo/grantAgreement/TUBITAK/SOBAG/118C316 | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.identifier.doi | 10.1039/d1gc04711f | en_US |
dc.institutionauthor | Kurt, Hasan | |
dc.identifier.wosquality | Q1 | en_US |
dc.identifier.wos | 000770048900001 | en_US |
dc.identifier.scopus | 2-s2.0-85127669630 | en_US |
dc.identifier.scopusquality | Q1 | en_US |